*NEWS****NEWS****NEWS****NEWS*
PD Dr. Andreas F.M. Kilbinger 3.11.2009
Institut für Organische Chemie "Heterotelechelic ring opening metathesis
Johannes Gutenberg Universität Mainz polymers"
Duesbergweg 10-14 Hilf, Kilbinger
D-55099 Mainz Macromolecules 2010, 43, 208
Germany
room 222.03.122
(N49°59.518',E8°13.956')
phone +49 (0)6131 3925359 14.7.2009
fax +49 (0)6131 3926106 "Polymeric Janus particles"
web www.kilbinger.net Wurm, Kilbinger
email akilbing@uni-mainz.de Angew. Chem. 2009, 48, 8412
20.10.2009
"Linear organo soluble poly(p-benzamide)s"
Seyler, Kilbinger
Macromolecules 2009, 42, 9141
page best viewed with Safari
last updated: 30.1.2010
visitors since 18.5.2004
Synthesis of shape persistent nano-objects
The direct synthesis of covalently bonded molecular objects on the nanometer scale is a great challenge.
The construction of such nanoscopic objects is often compared to building structures from Lego® bricks.
Therefore, let's look at some of the building blocks from a polymer chemist's point of view.
In the picture below, you can see a linear arrangement of the classic 2x4 Lego® brick. Each brick is connected to the next using just one of the brick's connectors. In polymer terms, this is the most typical way monomers are connected to each other - via one covalent bond only.
We can see from this kind of connection that the geometry of the final object is quite variable. Like a covalent single bond, we can easily rotate around the connection of two bricks. The object obtained is therefore not shape persistent.
However -and when building with Lego® bricks - we would do this intuitively: if we connect two bricks via two connectors at the same time, the final object obtained is indeed shape persistent (linear in the picture below).
Of course, we do not have to stop at linear structure. Other geometries are also possible and can be built in a shape persistent fashion. Below is a picture of a simple right angle turn which is also shape persistent because each of the building blocks is connected to the adjacent ones via two connectors.
As the 2x4 brick itself is shape persistent and we connect the bricks via two connectors at a time, we can design objects and predict shapes and geometries.
What does all of this have to do with synthetic chemistry?
When designing nanoscopic molecular objects, it is important to ensure that the monomer structure (building block) itself is shape persistent. In addition, the connection of the monomers (building blocks) must lead to predictable and uniquely defined geometries.
We believe that oligomers of aromatic amino acids such as p-aminobenzoic acid fulfill most of the above criteria.
Para-linked aminobenzoic acid oligomers form shape persistent linear rod-like chains. The phenyl rings are, in principle, free to rotate around the single bonds indicated. However, any rotation does not change the linear geometry of the structure.
Introducing alkyloxy side chains on the phenyl rings gives an altered scenario. Here, the phenyl rings are locked into place because of a hydrogen bond formed between the ether oxygens and the amide N-H-donor. The structure shown below can be compared to the Lego® bricks above that were linked via two connectors. Here, the two connectors are the covalent bond (amide bond) and the non-covalent bond (hydrogen bond).
Employing both types of bonds - covalent and non-covalent - will allow us to construct objects on the nanometer scale with predictable geometry.
We use a modified peptide synthesizer to assemble the objects in an automated fashion, similar to the way peptide chemists build peptides.
For further information you can read the following key publications on the subject:
"Hockey puck-micelles from oligo(p-benzamide)-b-PEG rod-coil block copolymers"
Schleuss, T.W.; Abbel, R.; Gross, M.; Schollmeyer, D.; Frey, H.; Maskos, M.; Berger, R.; Kilbinger, A.F.M.
Angew. Chem. Int. Ed. 2006, 45, 2969; Angew. Chem. 2006, 118, 3036
"Supramolecular PEG-co-oligo(p-benzamide)s prepared on a peptide synthesizer "
König, H.M.; Gorelik, T.; Kolb, U.; Kilbinger, A.F.M.
J. Am. Chem. Soc. 2007, 129, 704
End-functionalization reactions for the ring opening metathesis polymerization (ROMP)
Polymers carrying exactly one functional group at the chain end are particularly useful for a variety of applications. The functional end-group can be used to stick to a macroscopic surface or even the surface of a nano-particle. Such polymers are also used to construct more complex macromolecular architectures such as graft copolymers, stars or block copolymers. Another common use is the conjugation to bio-macromolecules or bio-oligomers such as for example peptides.
Figure 1. Applications for end-functional polymers
Many of the above applications rely on having exactly one functional end-group. Two instead of one end-group might be disastrous for many applications.
To illustrate this fact, imagine the following scenario: An end-functional polymer is polymerized via the functional end-group to give a graft copolymer. Now imagine that some of the polymers carry two instead of one end-group.
As the figure below shows, one polymerizable end-group will indeed lead to a graft copolymer but two or more end-groups will lead to uncontrolled branching and ill-defined products.
Figure 2. One, two = too many end-groups
To introduce functional end-groups to living polymers one can use two synthetic strategies:
- use a functional initiator
- terminate the propagating chain end functionally
The ring opening metathesis polymerization (ROMP) has many distinct advantages, the major one being its tolerance towards functional groups. In other words, it doesn't matter if the cyclic olefin that is being polymerized carries other functional groups such as aldehydes, amides, nitriles and many others.
However, because the propagating ruthenium carbene is so tolerant towards functional groups, there are virtually no reagents that can react with the ruthenium carbene to turn it into an end-functional group. If you compare this to anionic polymerization, the situation is quite different. The living and propagating carbanion is highly reactive and therefore tolerates almost no functional groups within the monomer structure. Due to this high reactivity, there are many possible reagents that will react with the carbanion to turn it into a useful functional end-group, such as epoxides, aldehydes, alkyl halides and many more.
Figure 3. General problems in end-functionalizing polymers
Our group has developed two methods to overcome the problem of ROMP end-functionalization. The first solution to the problem we termed Sacrificial Synthesis. It allows us to introduce alcohol and thiol end-groups to the chain end of a ROMP polymer.
The principle of Sacrificial Synthesis is outlined below: The monomer of choice is polymerized in the usual living manner with the ratio between the ruthenium initiator and monomer giving the molecular weight of the polymer. A second monomer is then added to this first block to produce a diblock copolymer. The second monomer, however, is cyclic only because of the "lock" holding the cycle together (see below). This "lock" allows us later on to cleave the entire second block bar the first half of the second monomer structure (in yellow below).
This results in exactly one functional group covalently attached to the first polymer block.
Figure 4. The principle of Sacrificial Synthesis
The following example shows how this general principle can be applied to real monomer structures.
Th first monomer to be polymerized is norbornene imide, the second one a dioxepine. The dioxepine is a cyclic olefin as well as a cyclic acetal and can later on be cleaved using acidic hydrolysis. This leaves exactly one hydroxy group at the chain end of the first polymer block.
Figure 5. Applying Sacrificial Synthesis to create hydroxy-functional end-groups
For more information you can read the following article:
"Mono-functional metathesis polymers via sacrificial diblock copolymers"
Hilf, S.; Berger-Nicoletti, E.; Grubbs, R.H.; Kilbinger, A.F.M.
Angew. Chem .Int. Ed. 2006 45, 8045; Angew. Chem. 2006, 118, 8214
New chromophores based on poly(thiopheneamide)s
coming soon
Aramide peptide conjugates
coming soon
Current students
Johannes Klos
"Synthesis of oligoamide based chromophores. "
Maren Schulze
"Synthesis of non-aggregating rigid rods"
Nils Hanik
"Synthesis of a universal end-capping reagent for ROMP"
Christof Storz
"Rigid rod-like templates for the immobilisation of magnetic nano particles"
Mark Schäfer
"Electroactive block copolymers via ROMP"
Alumni
Dr. Helga Seyler (Postdoc with Prof. Holmes, Melbourne)
"Synthesis of functional oligo(p-benzamide) heterosequences"
Dr. Stefan Hilf (Evonik Röhm GmbH)
"Synthesis of end-functionalized olefin metathesis polymers"
Dr. Tobias Schleuss (Sartorius)
"Synthesis and Characterization of aromatic amides and aramide -based block copolymers"
Dr. Hannah König (BASF)
"Solid-supported synthesis of aromatic oligo amides"
Dr. Robert Abbel
Diplomarbeit 2004: "Rod-Coil Block Copolymers with Monodisperse Oligoamide Rod Segments"
Ute Heerde
"Rod-coil-rod polymers based on telechelic ROMP polymers"
REFEREED PUBLICATIONS
2010
48. "Polythiopheneamides - a new class of chromophores"
Klos, J.; Hilf, S.; Kilbinger A.F.M.
submitted47. "Hairy aramide rod-coil copolymers"
Seyler, H.; Kilbinger, A.F.M.
submitted46. "H-bonding schemes of di- and tri-p-benzamides assessed by a combination of electron diffraction, X-ray powder diffraction and solid-state NMR"
Gorelik, T.; Matveeva, G.; Kolb, U.; Schleuß, T.; Kilbinger, A.F.M.; van de Streek, J.; Bohle, A.; Brunklaus, G.
Cryst. Eng. Comm. 2010 accepted
45. "Heterotelechelic ring opening metathesis polymers"
Hilf, S.; Kilbinger, A.F.M.
Macromolecules 2010, 43, 208
2009
44. "Long-chain Branched ROMP Polymers"
Hilf, S.; Wurm, F.; Kilbinger, A.F.M.
J. Polym. Sci. A 2009, 47, 693243. "Linear organo soluble poly(p-benzamide)s"
Seyler, H.; Kilbinger, A.F.M.
Macromolecules 2009, 42, 914142. "Functional end groups for polymers prepared using the ring-opening metathesis polymerisation"
Hilf, S.; Kilbinger, A.F.M.
Nature Chemistry 2009, 1, 53741. "Polymeric Janus particles"
Wurm, F.; Kilbinger A.F.M.
Angew. Chem. 2009, 48, 841240. "Ionic Liquids on Demand in Continuous Flow"
Wilms,D.; Klos, J.; Kilbinger, A.F.M.; Löwe, H.; Frey, H.
Org. Process Res. Dev. 2009, 13, 96139. "Polymerizable well-defined oligo(thiophenamide)s and their ROMP block-copolymers"
Hilf, S.; Klos, J.; Char, K.; Woo, H.; Kilbinger A.F.M.
Macromol. Rapid Commun. 2009, 30, 124938. "Thiol-functionalized ROMP polymers via Sacrificial Synthesis"
Hilf, S.; Kilbinger, A.F.M.
Macromolecules 2009, 42, 412737. "A facile synthesis of aramide-peptide amphiphiles"
Seyler, H.; Storz, C.; Abbel, R.; Kilbinger, A.F.M.
Soft Matter 2009, 5, 254336. "Molecular Organization of Cylindrical Sexithiophene Aggregates Measured by X-ray Scattering and Magnetic Alignment"
Gielen, J.C.;Wolffs, M.; Portale, G.;Bras, W.;Henze, O.; Kilbinger, A.F.M.; Feast, W.J.; Maan, J.C.; Schenning, A.P.H.J.; Christianen, P.C.M
Langmuir 2009, 25, 1272
35. "Sacrificial Synthesis of Hydroy-Telechelic Metathesis Polymers via Multiblock-copolymers"
Hilf, S.; Kilbinger, A.F.M.
Macromolecules 2009, 42, 1099
2008
34. "An improved rapid synthesis of oligo(p-benzamide) block copolymers"
König, H.M.; Kilbinger, A.F.M.
Macromol. Rapid Commun. 2008, 29, 172133."Sacrificial Synthesis of Hydroxy-functionalized ROMP polymers – An efficiency study"
Hilf, S.; Grubbs, R.H., Kilbinger, A.F.M.
Macromolecules 2008, 41, 600632."End Capping Ring-Opening Olefin Metathesis Polymerization Polymers with Vinyl Lactones"
Hilf, S.; Grubbs, R.H.; Kilbinger, A.F.M.
J. Am. Chem. Soc. 2008, 130, 1104031."Janus Micelles Induced by Olefin Metathesis"
Wurm, F.; König, H.M.; Hilf, S.; Kilbinger, A.F.M.
J. Am. Chem. Soc. 2008 130, 587630."Systematic Investigation of Functional Core Variation Within Hyperbranched Polyglycerols"
Barriau, E.; Pastor-Perez, L.; Berger-Nicoletti, E.; Kilbinger A.F.M.; Frey, H.; Stiriba, S.-E.
J. Polym.Sci A 2008, 46, 204929."Incorporation of a Photosensitizer-Core Within Hyperbranched Polyether Polyols: Effect of the Branched Shell on the Core Properties"
Pastor Pérez, L.; Barriau, E.; Berger-Nicoletti, E.; Kilbinger, A.F.M.; Pérez-Prieto, J.; Frey,H.; Stiriba, S.;
Macromolecules 2008, 41, 1189
28."A "Click" Approach to ROMP Block Copolymers"
Hilf, S.; Hanik, N.; Kilbinger, A.F.M.
J. Polym. Sci. A 2008, 46, 291327."A precursor route to supramolecular oligo(p-phenylene terephthalamide) block copolymers"
Tobias W. Schleuss, Dieter Schollmeyer, Andreas F.M. Kilbinger
Macromol. Rapid Commun. 2008, 29, 293
2007
26."Pencil Lead as a Matrix for MALDI-ToF Mass Spectrometry of Sensitive Functional Polymers"
Berger-Nicoletti, E.; Wurm, F.; Kilbinger, A.F.M.; Frey, H.
Macromolecules 2007, 40, 746
25."A Facile Two-Step Route to Branched Polyisoprenes via ABn-Macromonomers"
López-Villanueva, F.-J.; Wurm, F.; Kilbinger, A.F.M.; Frey, H.
Macromol. Rapid Comun. 2007, 28, 704
24."Rod-Coil Copolymers from Oligo(p-benzamide) Foldamers "
Seyler, H.; Berger-Nicoletti, E.; Kilbinger, A.F.M.*
J. Mater. Chem. 2007 17, 1954
23."Anharmonic Magnetic Deformation of Self-Assembled Molecular Nanocapsules"
Manyuhina, O.V.; Shklyarevskiy, I.O.; Jonkheim, P.; Christianen, P.C.M.; Fasolino, A.; Katsnelson, M.I.; Schenning, A.P.H.J.; Meijer, E.W.; Henze, O.; Kilbinger, A.F.M.; Feast, W.J.; Maan, J.C.
Phys. Rev. Lett. 2007, 98, 146101
22."An all-ROMP route to graft-copolymers"
Hilf, S.; Kilbinger, A.F.M.
Macromol. Rapid Commun. 2007, 28, 122521."Automated Large-Scale Synthesis of Supramolecular Oligo(p-benzamide) Block Copolymers"
Klos, J.; Wurm, F.; König, H.M.; Kilbinger, A.F.M.
Macromolecules 2007, 40, 782720."Supramolecular PEG-co-oligo(p-benzamide)s prepared on a peptide synthesizer "
König, H.M.; Gorelik, T.; Kolb, U.; Kilbinger, A.F.M.
J. Am. Chem. Soc. 2007, 129, 704 (featured in Synfacts 2007, 4, 437)
19."Learning from nature: ß-sheet mimicking copolymers get organized"
König, H.M.; Kilbinger, A.F.M.
Angew. Chem. Int. Ed. 2007, 46, 8334; Angew. Chem. 2007, 119, 8484
2006
18."Hockey puck-micelles from oligo(p-benzamide)-b-PEG rod-coil block copolymers"
Schleuss, T.W.; Abbel, R.; Gross, M.; Schollmeyer, D.; Frey, H.; Maskos, M.; Berger, R.; Kilbinger, A.F.M.
Angew. Chem. Int. Ed. 2006, 45, 2969; Angew. Chem. 2006, 118, 3036
17."Solid-Phase Synthesis of Oligo(p-benzamide) Foldamers"
König, H.M.; Abbel, R.; Schollmeyer, D.; Kilbinger, A.F.M.
Org. Lett. 2006, 8, 1819 (featured in Synfacts 2006, 7, 743)
16."Supramolecular Electronic Coupling in Chiral Oligothiophene Nanostructures"
Westenhoff, S.; Abrusci, A.; Feast, W.J.; Henze, O.; Kilbinger, A.F.M.; Schenning, A.P.H.J.; Silva, C.
Adv. Mater. 2006, 18, 1281
15."Mono-functional metathesis polymers via sacrificial diblock copolymers"
Hilf, S.; Berger-Nicoletti, E.; Grubbs, R.H.; Kilbinger, A.F.M.
Angew. Chem .Int. Ed. 2006 45, 8045; Angew. Chem. 2006, 118, 8214
(featured in Synfacts 2007, 2, 154 and in Nature,2007, 445, 271)
2005
14."Soluble Oligo-Aramide Precursors - a Novel Class of Building Blocks for Rod-Coil Architectures"
Abbel, R.; Frey, H.; Schollmeyer, D.; Kilbinger, A.F.M.
Chem. Eur. J. 2005, 11, 2170
13."Magnetic deformation of self-assembled sexithiophene spherical nanocapsules”
Shklyarevskiy, I.O.; Jonkheijm, P. ; Christianen, P.C.M.; Schenning, A.P.H.J.; Meijer, E.W.; Henze, O.; Kilbinger, A.F.M.; Feast, W.J.; Del Guerzo, A.; Desvergne, J.-P.; Maan, J.C.
J. Am. Chem. Soc. 2005 127, 1112
12."Rod-length dependent aggregation in a series of oligo(p-benzamide)-block-poly(ethylene glycol) rod-coil copolymers"
Abbel, R.; Schleuß, T.W.; Frey, H.; Kilbinger, A.F.M.
Macromol. Chem. Phys. 2005, 206, 2067
2004
200311."Surface-controlled self-assembly of chiral sexithiophenes"
Henze, O.; Biscarini, F.; Cavallini, M.; Feast, W.J.; Jonkheijm, P.; Kilbinger, A.F.M.; Lazzaroni, R.; Leclère, Ph.; Meijer, E.W.; Schenning, A.P.H.J.
J. Mater. Chem. 2004, 14, 1959
10."About Oligothiophene Self-Assembly: From Aggregation in Solution to Solid-State Nanostructures”
Leclere, Ph.;Surin, M.; Viville, P.; Lazzaroni, R.; Kilbinger, A.F.M.; Henze, O.; Feast, W.J.; Cavallini, M.; Biscarini, F.; Schenning, A.P.H.J. and Meijer, E.W.
Chem. Mater. 2004, 16, 4452
9."Oligoethyleneoxide functionalized sexithiophene organic field effect transistors"
Sandberg, H.; Henze, H.; Kilbinger, A.F.M.; Sirringhaus, H.; Feast, W.J.; Friend, R.H.
Synth. Met. 2003, 137, 885
8."Magic Ring Rotaxanes by Olefin Metathesis"
Kilbinger, A.F.M.; Cantrill, S.J.; Waltman, A.W.; Day, M.W.; Grubbs, R.H.
Angew. Chem. Int. Ed. 2003, 42, 3281; Angew. Chem. 2003, 115, 3403
2002
7."Supramolecular Organisation of a,a'-disubstituted Sexithiophenes"
Schenning, A.P.H.J.; Kilbinger, A.F.M.; Biscarini, F.; Cavallini, M.; Cooper, H.J.; Derrick, P.J.; Feast, W.J.; Lazzaroni, R.; Leclère, Ph.; McDonell, L.A.; Meijer, E.W.; Meskers, S.C.J.
J. Am. Chem. Soc. 2002, 124, 1269
6."Arene-perfluoroarene Interactions as Physical Cross-links for Hydrogel Formation"
Kilbinger, A.F.M.; Grubbs, R.H.
Angew. Chem. Int. Ed. 2002, 41, 1563; Angew. Chem. 2002, 114, 1633
2001
20005."Synthesis and properties of self organising semiconducting and luminescent polymers and model compounds"
Feast, W.J.; Goldoni, F.; Kilbinger, A.F.M.; Meijer, E.W.; Petty, M.C.; Schenning, A.P.H.J.
Macromolecular Symposia, 2001, 175, 151
4."Ultrathin organic films for field effect transistors"
Sandberg, H.G.; Henze, O.; Sirringhaus, H.; Kilbinger, A.; Feast, W.J. Friend, R.H.
Proc. SPIE, 2001, 4466, 35
3."Chiral Aggregates of a,a-di-Substituted Sexithiophenes in Protic and Aqueous Media"
Kilbinger, A.F.M.; Schenning, A.P.H.J.; Goldoni, F.; Feast, W.J.; Meijer, E.W.
J. Am. Chem. Soc. 2000, 122, 1820
2."Mass spectrometric evidence for aggregation of a substituted sexithiophene"
Kilbinger, A.F.M.; Cooper, H.J.; McDonnell, L.A.; Feast, W.J.; Derrick, P.J.; Schenning, A.P.H.J., Meijer, E.W.
Chem. Commun., 2000, 383
1."Solution processable alternating oligothiophene-PEO-block-co-polymers: synthesis and evidence for solvent dependent aggregation"
Kilbinger, A.F.M.; Feast, W.J.
J. Mater. Chem. 2000, 10, 1777
NON-REFEREED PUBLICATIONS
| 2009 | Stellvertretendes Mitglied im Leitungsgremium des Gutenberg-Forschungskollegs der Johannes Gutenberg-Universität Mainz
|
| 2008 | Award of the Emil und Paul Müller-Gedächtnisstiftung
|
| 12.12.2007 | Habilitation in Organic Chemistry
|
| 2007 | "Dr. Hermann Schnell Award" of the Dr. Hermann Schnell foundation (GDCh) for the best young
|
| 2006 | Research support awarded by Boehringer Ingelheim
|
| July 2006 | Feodor Lynen Follow-up Research Fellowship, Alexander von Humboldt Foundation
|
| 2003 - | "Wissenschaftlicher Mitarbeiter" in the group of Prof. Holger Frey
|
| 2000-2002 | Postdoc at the California Institute of Technology in the group of Prof. R.H. Grubbs (Nobel Prize in Chemistry 2005)
|
| 1999-2000 | Postdoc at the IRC in Polymer Science, University of Durham, group of Prof. W.J. Feast, FRS
|
| 1996-1999 | PhD (Dunelm) PhD in synthetic polymer chemistry at the IRC in Polymer Science and Technology, University of Durham, UK
|
| 1996 | Diplom, Chemistry Free University of Berlin
|
| 1993 | Vordiplom, Chemistry Johannes Gutenberg University Mainz
|
| 1991 | Abitur
|
| 1971 | born in Mainz, Germany |
PD Dr. Andreas F.M. Kilbinger |
|
Privatdozent since 12/2007 |
|
| age 38 h-Index=16 | |
| PhD: W.J. Feast, Durham | |
| Postdoc: R.H. Grubbs, Caltech | |
| Dr. Hermann Schnell Award (German Chemical Society) | |
| Feodor Lynen Research Fellowship (Humboldt-Foundation) | |
| Stellvertretendes Mitglied im Leitungsgremium des Gutenberg-Forschungskollegs der Johannes Gutenberg-Universität Mainz | |
|
|
publications in high impact journals Nature Chemistry 1 Angewandte Chemie 6 J. Am. Chem. Soc. 6 Adv. Mater. 1 |
|
back in WS 09/10
SFB 625
Collaborative Research Centre 625
From Single Molecules to Nanoscopically Structured Materials
IRTG
International Research Training Group (IRTG)
"Self-organized Materials for Optoelectronics"
POLY Symposium
Non-conventional functional block copolymers
ACS National Meeting,
March 21-25, 2010, San Francisco.
A symposium entitled "Non-conventional functional block copolymers" will be held at the 239th American Chemical Society National Meeting in San Francisco on March 21-25, 2010. This symposium will address recent developments in the synthesis, characterization and application of block copolymers that are of non-conventional nature.
This includes:
(i) rod-coil block copolymers
(ii) organic-inorganic block copolymers
(iii) stimuli-responsive block copolymers
(iv) degradable block copolymers
(v) orthogonal reactive block copolymers
(vi) orthogonal synthesis of block copolymers, and
(vii) multiblock copolymers.
The interdisciplinary use of block copolymers will be strongly emphasized during the symposium and we kindly invite you to participate in the promotion of non-conventional functional block copolymers for future applications. Confirmed Invited speakers:
1) Prof. Dr. Andreas Herrmann (University of Groningen, NL)
2) Prof. Dr. Axel Müller (Universität Bayreuth, D)
3) Prof. Dr. Timothy J. Deming (University of California, Los Angeles, USA)
4) Prof. Dr. David M. Haddleton (University of Warwick, UK)
5) Prof. Dr. Marc Hillmyer (University of Minnesota, USA)
6) Prof. Dr. Justin L. Mynar (The University of Tokyo, JP)
7) Prof. Dr. Ian Manners (University of Bristol, UK)
8) Prof. Dr. Tom Russell (University of Massachusetts, USA)
9) Prof. Dr. Gregory N. Tew (University of Massachusetts, USA)
10) Prof. Dr. Jan van Hest (Radboud University Nijmegen, NL)
We cordially invite you to submit Oral and/or Poster presentations in research areas listed above or on related topics. Abstracts and preprints are due on October 19th, 2009 and have to be submitted through the OASYS website:
For further information on the symposium please visit: http://www.theato.net/ Please contact us if you have any questions!
Organizers
Patrick Theato, Institute of Organic Chemistry, Department of Chemistry, Pharmacy and Geosciences, Johannes Gutenberg University Mainz, Duesbergweg 10-14, D-55099 Mainz, Germany, Tel: +49-(0)6131-3926256, Fax: +49-(0)6131-3924778, Email: theato@uni-mainz.de
Andreas Kilbinger, Institute of Organic Chemistry, Department of Chemistry, Pharmacy and Geosciences, Johannes Gutenberg University Mainz, Duesbergweg 10-14, D-55099 Mainz, Germany, Tel: +49-(0)6131-3925359, Fax: +49-(0)6131-3926106, Email: akilbing@uni-mainz.de
E. Bryan Coughlin, Department of Polymer Science & Engineering, University of Massachusetts, 120 Governors Drive, Amherst MA, 01003-4530, Tel: +1-413-577-1616, Fax: +1-413-545-0082, Email: coughlin@mail.pse.umass.edu
Sponsors
We are looking for sponsors. Please feel free to contact us!
2008
|
Award of the Emil und Paul Müller-Gedächtnisstiftung
|
2007 - 2010
|
"Synthesis of mono-functional olefin metathesis polymers", Deutsche Forschungsgemeinschaft (DFG), Individual Grant
|
2007
|
"Supramolecular aramide-blockcopolymers for compatibilization of Kevlar-composites", Johannes Gutenberg-Universität
|
2006 - 2011
|
"Self-organized materials for optoelectronics", Deutsche Forschungsgemeinschaft (DFG), "International Research Training Group" between Mainz/Germany and Seoul/Korea
|
2006 - 2009
|
"Synthesis and investigation of supramolecular order in block copolymers from coil-blocks and shape persistent nanoscopic objects", Deutsche Forschungsgemeinschaft (DFG), Individual Grant
|
2006
|
"Synthesis of mono-functional olefin metathesis polymers", Alexander von Humboldt-Foundation, Feodor Lynen Follow-up
|
2006
|
Boehringer Ingelheim supports the research on "Thermoplastic elastomers via ring opening metathesis co-polymerization of
|
2005 - 2009
|
"From single molecules to nanoscopically structured materials", Deutsche Forschungsgemeinschaft (DFG), member of the
|
2004
|
"Oligoaramide β-sheet mimetics as non-covalent cross-linkers in fibre forming polymers", Johannes Gutenberg-Universität Mainz Research Fund
|
2003 - 2008
|
Young Investigators Grant, "Fonds der Chemischen Industrie" (German Chemical Industry Fund)
|
2003
|
"Development of new synthetic concepts for monodisperse synthetic condensation polymers: new materials properties through supramolecular order", Johannes Gutenberg-Universität Mainz Research Fund |
Univ.-Prof. Dr. Holger Frey; Dr. Andreas Kilbinger |
Mi, 22. Apr. 2009 - Do, 23. Jul. 2009 |
|
Einführung in die Makromolekulare Chemie; Teil 1: Herst. von Polymeren |
Dr. Andreas Kilbinger; Dr. Patrick Theato |
Do, 23. Apr. 2009 - Do, 23. Jul. 2009 |
Dr. Andreas Kilbinger; Dr. Patrick Theato |
k.Terminbuchung |
|
Dr. Heiner Detert; Dr. Anja Hoffmann-Röder; Dr. Andreas Kilbinger; Univ.-Prof. Dr. Udo Nubbemeyer; Dr. Patrick Theato |
Mo, 20. Apr. 2009 - Fr, 24. Jul. 2009 |
|
Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren |
Dr. Andreas Kilbinger; Dr. Patrick Theato |
k.Terminbuchung |
Dr. Andreas Kilbinger; Dr. Patrick Theato |
Mo, 20. Apr. 2009 - Mo, 20. Jul. 2009 |
|
Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese |
Univ.-Prof. Dr. Holger Frey; Dr. Andreas Kilbinger; Dr. Michael Maskos; Univ.-Prof. Dr. Manfred Schmidt; Dr. Patrick Theato; Univ.-Prof. Dr. Rudolf Zentel |
k.Terminbuchung |
Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren |
Univ.-Prof. Dr. Holger Frey; Dr. Andreas Kilbinger; Dr. Michael Maskos; PD Dr. Wolfgang Schärtl; Univ.-Prof. Dr. Manfred Schmidt; Dr. Patrick Theato |
k.Terminbuchung |
Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere |
Univ.-Prof. Dr. Holger Frey; Dr. Andreas Kilbinger; Univ.-Prof. Dr. Manfred Schmidt; Univ.-Prof. Dr. Hans Spiess; Dr. Patrick Theato; Univ.-Prof. Dr. Rudolf Zentel |
k.Terminbuchung |
Seminar über Forschungsarbeiten aus dem Institut für Organische Chemie |
Dr. Anja Hoffmann-Röder; Dr. Andreas Kilbinger; Dr. Patrick Theato |
Mi, 22. Apr. 2009 - Mi, 22. Jul. 2009
|
| Chemie für Biologen Vorlesung; 4 SWS; Diese Vorlesung ist identisch mit der Experimentalvorlesung "Einführung in die Organische Chemie"; Mi, Do, 8:00 - 10:00, Hörsaal C01 |
Löwe, H. Kilbinger, A. |
||||
| Einführung in die makromolekulare Chemie; Teil 1: Herstellung von Polymeren Vorlesung; 2 SWS; 6. Std. Pl. Sem.; Do, 11:00 - 13:00, Hs 22, Seminarraum C04, C05; Bezüglich des Raumes bitte unbedingt evtl. Änderungen zu Semesterbeginn beachten, da noch nicht sichergestellt ist, dass der neue Seminarraum C04 zu diesem Zeitpunkt fertiggestellt ist. |
Kilbinger, A. Frey, H. |
||||
| Experimentalvorlesung: Einführung in die Organische Chemie Vorlesung; 4 SWS; ECTS: 5; 2. Stud.pl.-Sem.; Mi, Do, 8:00 - 10:00, Hörsaal C01; Einzeltermin am 14.2.2009, 9:30 - 12:30, Hs 22, Hörsaal C01, S 1; Tutoriumstermine werden in der Vorlesung bekannt gegeben |
Löwe, H. Kilbinger, A. |
||||
| Übungen zur Experimentalvorlesung: Einführung in die Organische Chemie Übung; Di, Do, 9:00 - 11:00, SR 111; Di, Mi, 10:00 - 12:00, Hs 21; Di, 14:00 - 16:00, Hs 21; Di, 11:00 - 12:00, 12:00 - 13:00, 13:00 - 14:00, 14:00 - 15:00, SR 134; Do, 9:00 - 11:00, Seminarraum C04 |
Löwe, H. Kilbinger, A. wiss. Mitarbeiter |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Maskos, M. Théato, P. Kilbinger, A. Schmidt, M. |
||||
| Seminar zum Grundmodul in Makromolekularer Chemie 1 + 2 Seminar; Mo, 15:00 - 17:00, SR 134 |
Maskos, M. Kilbinger, A. Théato, P. Frey, H. Zentel, R. |
||||
| Organische Analytik und Spektroskopie Seminar; entspricht Vorkurs OC-F; Blockveranstaltung, 13.10.2008 9:00 - 16.10.2008 18:00, Hs 23; Einzeltermin am 17.10.2008, 9:00 - 15:00, Hs 23 |
Detert, H. Hoffmann-Röder, A. Kilbinger, A. Théato, P. |
||||
| Seminar für Praktikanten Seminar; 5. Stud. pl.-Sem.; Mo, 17:00 - 19:00, SR 132; Fr, 15:00 - 17:00, SR 132 |
Kunz, H. Nubbemeyer, U. Detert, H. Hoffmann-Röder, A. Théato, P. Kilbinger, A. |
||||
| Seminar über Forschungsarbeiten aus dem Institut für Organische Chemie Seminar; 1 SWS; jede 2. Woche Mi, 17:00 - 19:00, SR 132; jede 2. Woche Mi |
Kilbinger, A. Théato, P. Hoffmann-Röder, A. |
||||
| Supramolekulare Polymere, Hybrid-Materialien aus synthetischen und natürlichen Makromolekülen Vorlesung; 2 SWS; Di, 17:00 - 19:00, Hs 23; Di, 17:00 - 19:00, Hörsaal C03; Einführung am 21.10.08 im HS 23 |
Kilbinger, A. | ||||
| Tutorien zur Chemie für Biologen (1. Semester) [TChfB] Tutorium; 2 SWS; ECTS: 3; Mo, 15:00 - 17:00, SR 132; Do, 11:00 - 13:00, SR 134, SR 111, SR J; Do, 12:00 - 14:00, SR 107, Seminarraum E 01-231; Mi, 15:00 - 17:00, SR 111, SR J; Mo, 15:15 - 17:00, SR 111; Di, 17:00 - 19:00, SR 134 |
Löwe, H. Kilbinger, A. N. N. |
||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR 132, SR J |
Théato, P. Maskos, M. Kilbinger, A. Frey, H. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Théato, P. Zentel, R. Kilbinger, A. Schmidt, M. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Schärtl, W. Schmidt, M. Kilbinger, A. Théato, P. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Einzeltermine am 26.9.2008, 9:00 - 13:00, SR 132; 6.10.2008, 9:00 - 18:00, SR 132 |
Frey, H. Schmidt, M. Zentel, R. Kilbinger, A. Théato, P. |
||||
| Chemie für Biologen [CfB Vorl.] Vorlesung; 6 SWS; - Die Veranstaltung ist mittwochs und donnerstags identisch mit der Experimentalvorlesung: Einführung in die Organische Chemie!; ab 30.4.2008; Die Vorlesung findet statt: Mi, Do 8:00 - 10:00, Hs 22 (Experimentalvorlesung) |
Löwe, H. Kilbinger, A. N. N. |
||||
| Experimentalvorlesung: Einführung in die Organische Chemie [OC-0] Vorlesung; 2. Stud.pl.-Sem.; Mi, Do, 8:00 - 10:00, Hs 22; Einzeltermin am 25.7.2008, 10:00 - 13:00, Hs 22, Hs 23; ab 30.4.2008 |
Löwe, H. Kilbinger, A. N. N. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren [Makro 1] Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Kilbinger, A. Théato, P. Zentel, R. Schmidt, M. Frey, H. |
||||
| Seminar zum Grundmodul in Makromolekularer Chemie 1 + 2 [Sem. Makro 1+2] Seminar; Mo, 15:00 - 17:00, SR J |
Maskos, M. Théato, P. Frey, H. Kilbinger, A. Zentel, R. |
||||
| Organische Analytik und Spektroskopie [Analyt. Prakt.] Praktikum; Blockveranstaltung 7.4.2008-11.4.2008 Mo-Fr, 12:00 - 18:00, Saal 221.02.115, Saal 221.02.123; Blockveranstaltung 7.4.2008-11.4.2008 Mo-Fr, 9:00 - 12:00, Hs 23 |
Detert, H. Hoffmann-Röder, A. Théato, P. Kilbinger, A. |
||||
| Seminar für Praktikanten [Prakt.-Sem.] Seminar; 5. Stud. pl.-Sem.; Mo, 17:00 - 19:00, SR 132; Fr, 15:00 - 17:00, SR 132 |
Kunz, H. Detert, H. Nubbemeyer, U. Hoffmann-Röder, A. Théato, P. Kilbinger, A. Witulski, B. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Zentel, R. Théato, P. Kilbinger, A. Schmidt, M. Maskos, M. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Kilbinger, A. Maskos, M. Schmidt, M. Théato, P. Schärtl, W. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Schmidt, M. Zentel, R. Théato, P. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Maskos, M. Théato, P. Kilbinger, A. |
||||
| Supramolekulare Polymere, Hybrid-Materialien aus synthetischen und natürlichen Makromolekülen Vorlesung; 2 SWS; Di, 17:00 - 19:00, Hs 23 |
Kilbinger, A. | ||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR 132, SR J |
Théato, P. Maskos, M. Kilbinger, A. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Théato, P. Zentel, R. Kilbinger, A. Schmidt, M. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Schärtl, W. Schmidt, M. Kilbinger, A. Théato, P. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Vorbesprechung am 03.09.2007 im SR 132 |
Frey, H. Schmidt, M. Zentel, R. Kilbinger, A. Théato, P. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; Einzeltermin am 8.10.2007, 14:00 - 16:00, SR 111, SR 107; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Théato, P. Zentel, R. Schmidt, M. Kilbinger, A. Maskos, M. |
||||
| Grundmodul in Makromolekularer Chemie 2 - Charakterisierung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung; Einzeltermin am 4.10.2007, 14:00 - 16:00, Hs 21 |
Frey, H. Maskos, M. Schmidt, M. Zentel, R. Kilbinger, A. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Zentel, R. Théato, P. Kilbinger, A. Schmidt, M. Maskos, M. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Kilbinger, A. Maskos, M. Schmidt, M. Théato, P. Schärtl, W. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Schmidt, M. Zentel, R. Théato, P. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Schmidt, M. Théato, P. Kilbinger, A. Maskos, M. |
||||
| Supramolekulare Polymere, Hybrid-Materialien aus synthetischen und natürlichen Makromolekülen Vorlesung; 2 SWS; Di, 17:00 - 19:00, Hs 23; Einzeltermine am 27.10.2006, 15:00 - 16:00, SR 107; 19.1.2007, 26.1.2007, 11:00 - 13:00, SR 132; 7.2.2007, 17:00 - 20:00, Hs 23 |
Kilbinger, A. | ||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR 132, SR J |
Frey, H. Maskos, M. Kilbinger, A. Théato, P. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 1 - Forschungsnahe Polymersynthese Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Théato, P. Zentel, R. Kilbinger, A. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Schärtl, W. Schmidt, M. Kilbinger, A. Théato, P. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Schmidt, M. Zentel, R. Kilbinger, A. Théato, P. |
||||
| Chemie für Biologen Vorlesung; 6 SWS; - Die Veranstaltung ist dienstags und donnerstags identisch mit der Experimentalvorlesung: Einführung in die Organische Chemie!; Di, Do, 8:00 - 10:00, Raum n.V.; Fr, 11:00 - 13:00, Hs 22; Einzeltermine am 5.8.2006, 11.9.2006, 10:00 - 13:00, Hs 22; 5.8.2006, 10:00 - 13:00, P 1; 11.9.2006, 10:00 - 13:00, Audi Max; Die Einteilung findet in der 1. Vorlesung GrHS der Chemie statt - max. 20 Studierende pro Termin. |
Kilbinger, A. Detert, H. |
||||
| Chemie für Biologen Tutorium; 1 SWS; Mo, 16:00 - 19:00, SR 107; Do, 11:00 - 13:00, SR 132; Mi, 15:00 - 17:00, SR J; Mi, 17:00 - 19:00, Lorentz-Raum 05-127; Einteilung in der Vorlesung |
Detert, H. Kilbinger, A. |
||||
| Einführung in die makromolekulare Chemie; Teil 1: Herstellung von Polymeren Vorlesung; 2 SWS; 6. Std. Pl. Sem.; Do, 11:00 - 13:00, Hs 23; Einzeltermine am 10.7.2006, 17:00 - 20:00, Hs 23; 11.10.2006, 15:00 - 18:00, SR 132 |
Frey, H. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Schmidt, M. Théato, P. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Schmidt, M. Théato, P. Kilbinger, A. |
||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR J; Der Seminarraum J befindet sich im Inst. f. Physikalische Chemie! |
Maskos, M. Kilbinger, A. Théato, P. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 2 - Struktur und Eigenschaften von Polymeren Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Maskos, M. Schärtl, W. Schmidt, M. Kilbinger, A. |
||||
| Wahlpflichtmodul in Makromolekularer Chemie 3 - Biopolymere und biokompatible Polymere Praktikum; ECTS: 10; Zeit und Raum n.V. |
Frey, H. Schmidt, M. Zentel, R. Kilbinger, A. Théato, P. |
||||
| Chemie für Biologen Vorlesung; 6 SWS; - Die Veranstaltung ist dienstags und donnerstags identisch mit der Experimentalvorlesung: Einführung in die Organische Chemie!; Di, Do, 8:00 - 10:00, Hs 22; Fr, 11:00 - 13:00, Hs 22; Einzeltermine am 2.8.2005, 9:00 - 12:00, Hs 22, S 1; 5.9.2005, 9:00 - 12:00, Hs 22, S 1; ab 28.4.2005; Die Einteilung findet in der 1. Vorlesung GrHS der Chemie statt - max. 20 Studierende pro Termin. |
Frey, H. Kilbinger, A. |
||||
| Chemie für Biologen Tutorium; 1 SWS; Mo, 16:00 - 19:00, SR 107; Do, 11:00 - 13:00, SR 132; Mi, 15:00 - 17:00, SR J; Di, 17:00 - 19:00, SR 107; Einteilung in der Vorlesung |
Frey, H. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; ECTS: 10; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Schmidt, M. Théato, P. Kilbinger, A. |
||||
| Übungen zur Experimentalvorlesung Einführung in die Organische Chemie Übung; 1 SWS; Mi, Mo, 12:00 - 13:00, SR 132; Do, 10:00 - 11:00, SR 132, Seminarraum A 01-219, SR 134; Mi, 12:00 - 13:00, SR 134; Mo, 12:00 - 13:00, Seminarraum A 01-219; Einzeltermin am 25.5.2005, 18:00 - 19:00, SR 132, SR 134 |
Frey, H. Kilbinger, A. wiss. Mitarbeiter |
||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR J; Der Seminarraum J befindet sich im Inst. f. Physikalische Chemie! |
Maskos, M. Kilbinger, A. Théato, P. |
||||
| Chemie für Biologen Vorlesung; 6 SWS; Di, Do, 8:00 - 10:00, Hs 22; Fr, 11:00 - 13:00, Hs 22; Einzeltermine am 27.7.2004, 18:30 - 20:30, Hs 22, P 1; 2.8.2004, 15:00 - 18:00, SR 132; 8.10.2004, 9:00 - 12:00, Hs 22, S 1; Die Einteilung findet in der 1. Vorlesung, 27.04., 8.00 Uhr GrHS der Chemie statt - max. 20 Studierende pro Termin. |
Zentel, R. Kilbinger, A. |
||||
| Grundmodul in Makromolekularer Chemie 1 - Herstellung von Polymeren Praktikum; 4 Wochen ganztägig nach Vereinbarung |
Frey, H. Zentel, R. Schmidt, M. Théato, P. Kilbinger, A. |
||||
| Übungen zur Einführung in die makromolekulare Chemie Übung; Do, 10:00 - 11:00, SR J; Der Seminarraum J befindet sich im Inst. f. Physikalische Chemie! |
Maskos, M. Kilbinger, A. |
||||